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- W2116720187 abstract "The reaction of glycidyloxydimethylphenyl silane with aniline was used as a model system to study the reactivity of silicon-based epoxy monomers. The reaction was monitored online by near-infrared spectroscopy, and the evolution of the concentration of each species throughout the reaction was determined by the application of multivariate curve resolution/alternating least squares to the set of recorded spectra. The reactivity was evaluated by a comparison of the concentration profiles obtained for the glycidyloxydimethylphenyl silane/aniline system with those of phenylglycidyl ether/aniline as a reference system. The results confirmed that the reactivity of the silicon-based epoxy monomer was higher and that its ring opening reaction was faster because of electronic effects. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1447–1456, 2006" @default.
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- W2116720187 date "2006-01-01" @default.
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- W2116720187 title "Reactivity of silicon-based epoxy monomers as studied by near-infrared spectroscopy and multivariate curve resolution methods" @default.
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- W2116720187 doi "https://doi.org/10.1002/pola.21254" @default.
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