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• W2116733430 abstract "Catalytic amounts of a protic reagent such as tert-butyl alcohol promote the isomerization of a stable amino-aryl-carbene into a transient azomethine ylide. Deprotonation of an alkyl-aldiminium salt also leads to a transient azomethine ylide, but labeling experiments rule out the transient formation of the corresponding amino-alkyl-carbene. The potential hypersurface between model amino-carbene, aziridine, and azomethine ylide is investigated." @default.
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• W2116733430 date "2002-12-20" @default.
• W2116733430 modified "2023-10-15" @default.
• W2116733430 title "Transient Azomethine-ylides from a Stable Amino-carbene and an Aldiminium Salt" @default.
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• W2116733430 doi "https://doi.org/10.1021/jo026214b" @default.
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