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- W2116746573 abstract "Previous articles have reported the progress made in enhancing the durability of a polyamide powder coating through the incorporation of an aminosilane. This work has been extended, and this paper is concerned mainly with the use of high mass resolution ToF-SIMS to refine the understanding of the role of the aminosilane in enhancing adhesion. After delamination of the coatings in a salt-spray cabinet, the presence of silane is easily detected on both sides of the failed interface. The silane has cross-linked; fragments attributed to this polymerisation are observed on the delaminated coatings and the exposed steel. At nominal mass 100, a peak assigned to FeOSi + fragment is readily observed and can be attributed to the formation of a covalent bond between iron and silane and the presence of an iron silicon oxide. The silicon Auger parameter obtained on the steel surface is consistent with this hypothesis." @default.
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- W2116746573 date "2006-01-01" @default.
- W2116746573 modified "2023-09-23" @default.
- W2116746573 title "Mechanism of delamination of a polyamide coating modified with an aminosilane" @default.
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- W2116746573 doi "https://doi.org/10.1002/sia.2213" @default.
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