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- W2116773835 abstract "Me3NO activation of the methylidyne-bridged cluster HRu3(CO)10(μ-COMe) (1) in the presence of the unsaturated diphosphine ligand 2,3-bis(diphenylphosphino)maleic anhydride (bma) furnishes the bma-substituted cluster HRu3(CO)8(bma)(μ-COMe) (2) and the diphenylphosphine-substituted cluster HRu3(CO)8(Ph2PH)[μ-PPh2C=CC(O)OC(O)] (3) as the major and minor products, respectively. The 1H and 31P NMR data indicate that the bma ligand in cluster 2 is chelated to one of the ruthenium atoms that is bridged by the hydride and methylidyne ligands. Cluster 3 has been fully characterized in solution by IR and NMR spectroscopies, and the solid-state structure determined by X-ray crystallography. 3 crystallizes in the monoclinic space P21, a = 12.1467(7) Å, b = 19.284(1) Å, c = 16.867(1) Å, β = 109.639(6)°, V = 3721.0(4) Å3, Z = 4, and dcalcd = 1.774 g cm−3; R = 0.0325, R w = 0.0383 for 3518 reflections with I > 3σ(I). The X-ray data confirm that one of the P–C(maleic anhydride) bonds of the bma ligand has been cleaved and that cluster 3 contains Ph2PH and μ-PPh2C=CC(O)OC(O) ligands, the latter which functions as a face-capping ligand to all three ruthenium atoms. Control experiments indicate that cluster 2 does not function as a precursor to cluster 3 under the employed reaction conditions." @default.
- W2116773835 created "2016-06-24" @default.
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- W2116773835 date "2007-05-11" @default.
- W2116773835 modified "2023-09-27" @default.
- W2116773835 title "Reaction of HRu3(CO)10(μ-COMe) with bma: NMR and X-ray structural evidence for the formation of the Ph2PH-substituted cluster HRu3(CO)8(Ph2PH)[μ-PPh2C=CC(O)OC(O)]" @default.
- W2116773835 cites W1523492729 @default.
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- W2116773835 doi "https://doi.org/10.1080/00958970601032515" @default.
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