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- W2116795644 abstract "Novel T-shape three-coordinate nickel(I) chlorides bearing an N-heterocyclic carbene ligand, NiCl(IPr)(2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene), were isolated by a reaction of Ni(0)(NHC)(2) with aryl chlorides. This Ni(I) complex was shown to act as a catalyst in a cross-coupling reaction of aryl halides with phenylmagnesium chloride." @default.
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- W2116795644 date "2010-01-01" @default.
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- W2116795644 title "A new aspect of nickel-catalyzed Grignard cross-coupling reactions: selective synthesis, structure, and catalytic behavior of a T-shape three-coordinate nickel(i) chloride bearing a bulky NHC ligand" @default.
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- W2116795644 doi "https://doi.org/10.1039/b924716e" @default.
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