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- W2116796254 abstract "Crystal structure investigations reveal that η3-lithio-1,3,3-triphenylpropyne-(diethyl ether)2 [6 · (OEt2)2] is of the propargyl structural type while [1-lithio-1-(2-methoxyphenyl)-3,3-diphenylallene-(diethyl ether)]2 {[7 · OEt2]2} is of the allenyl type. The assignment of the different structural types is mainly based on a comparison of the bond lengths C1-C2 and C2-C3 as well as of the difference ΔCC of these two bond lengths with the corresponding values of theoretical models of the propargyl and allenyl type. This leads also to a correction of an earlier assigned structural type." @default.
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- W2116796254 date "1995-03-01" @default.
- W2116796254 modified "2023-10-17" @default.
- W2116796254 title "Crystal Structure of η3-lithio-1,3,3-triphenylpropyne-(diethyl ether)2 and [1-lithio-1-(2-methoxyphenyl)-3,3-diphenylallene–diethyl ether]2: Propargyl- versus allenyl-type structures" @default.
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- W2116796254 doi "https://doi.org/10.1002/jlac.199519950361" @default.
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