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- W2116837318 abstract "We demonstrate that reactions between various 1-indanones and (SS)-N-tert-butanesulfinyl-(3,3,3)-trifluoroacetaldimine, conducted in the presence of catalytic amounts of LDA, occur with virtually complete stereochemical outcome, offering reliable and generalized access to biologically relevant β-trifluoromethyl-β-amino indanone derivatives. The products can be isolated in diastereomerically pure form simply by washing the crude reaction mixture with hexanes, underscoring practicality of the present method." @default.
- W2116837318 created "2016-06-24" @default.
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- W2116837318 date "2014-01-01" @default.
- W2116837318 modified "2023-10-18" @default.
- W2116837318 title "LDA-promoted asymmetric synthesis of β-trifluoromethyl-β-amino indanone derivatives with virtually complete stereochemical outcome" @default.
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- W2116837318 doi "https://doi.org/10.1039/c3ra45773g" @default.
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