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- W2116840897 abstract "The products of steady state UV irradiation of amino acidatobis(2,2′-bipyridine)cobalt(III) complexes have been identified. The products of these photodecarboxylation reactions include a carbonyl compound derived from the amino acid side chain. The viability of an aminocyclopropylmethyl radical clock as a potential mechanistic probe for the reaction was assessed by ab initio methods. The required cyclopropylglycine containing substrate was synthesized and used to show that reaction of an α-carbon centred radical must be a fast step if it occurs in the reaction sequence leading to formation of the intermediate metallacyclic complexes." @default.
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- W2116840897 date "1999-01-01" @default.
- W2116840897 modified "2023-09-25" @default.
- W2116840897 title "Use of a radical clock to study the photodecarboxylation of amino acidatocobalt(III) complexes †" @default.
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- W2116840897 doi "https://doi.org/10.1039/a904451e" @default.
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