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- W2116943919 abstract "Electrochemistry of saccharinate anion (sacc−) is studied at the liquid water|nitrobenzene (w|nb) interface by means of three-phase electrodes. Saccharinate anion can be effectively transferred across w|nb interface driven by the redox transformation of the lutetium bis(tetra-tert-butylphthalocyaninato), with a standard Gibbs energy of transfer from water to nitrobenzene of 20.17 kJ mol−1. The kinetics of transfer is estimated applying the quasireversible maximum. In addition, the influence of sacc− on the thermodynamics and kinetics of the alkali metal cations transfer is discussed." @default.
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- W2116943919 date "2011-12-01" @default.
- W2116943919 modified "2023-09-25" @default.
- W2116943919 title "Electrochemistry of saccharinate anion at liquid interfaces" @default.
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- W2116943919 doi "https://doi.org/10.1016/j.elecom.2011.09.030" @default.
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