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- W2116946557 abstract "Abstract (6‐Methoxy‐2‐oxo‐2 H ‐naphtho[1,2‐ b ]pyran‐4‐yl)methyl esters of valine or phenylalanine as model bifunctional molecules were synthesised to assess its applicability as a photocleavable protecting group for solution phase organic synthesis and in caging applications at longer wavelengths. The behaviour of the corresponding derivatives towards photolysis was evaluated by irradiation at 350 and 419 nm in a mixture of HEPES buffer and acetonitrile or methanol in a photochemical reactor, followed by HPLC/UV monitoring. Time‐resolved fluorescence measurements were used to elucidate the dynamics." @default.
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- W2116946557 date "2011-08-09" @default.
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- W2116946557 title "Long-Wavelength Photolysis of Amino Acid 6-(Methoxy-2-oxo-2H-naphtho[1,2-b]pyran-4-yl)methyl Esters" @default.
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- W2116946557 doi "https://doi.org/10.1002/ejoc.201100391" @default.
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