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• W2116947162 abstract "p-Methoxyphenyl (pMP) β-d-glycopyranosides (Glc, Gal, GlcNPhth, GalNPhth, GlcNTroc, Galβ4Glc, Galα4Gal) were prepared from the corresponding 1-O-acetyl sugars in 79–90% yield, using boron trifluoride etherate as promoter. Treatment of the pMP glycosides with acyl chlorides or bromides in the presence of various Lewis acids gave the corresponding glycosyl chlorides and bromides in 81–98% yield. Treatment of the acyl-protected pMP glycosides with thiophenol and boron trifluoride etherate gave the corresponding thioglycosides in 80–100% yield and high (> 20:1) β/α selectivity. The stability of pMP glycosides was investigated against a series of reagents." @default.
• W2116947162 created "2016-06-24" @default.
• W2116947162 creator A5044308797 @default.
• W2116947162 creator A5087190927 @default.
• W2116947162 date "1996-12-01" @default.
• W2116947162 modified "2023-10-07" @default.
• W2116947162 title "Conversion of p-methoxyphenyl glycosides into the corresponding glycosyl chlorides and bromides, and into thiophenyl glycosides" @default.
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• W2116947162 doi "https://doi.org/10.1016/s0008-6215(96)90118-4" @default.
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