Matches in SemOpenAlex for { <https://semopenalex.org/work/W2116965144> ?p ?o ?g. }
- W2116965144 endingPage "1633" @default.
- W2116965144 startingPage "1633" @default.
- W2116965144 abstract "An efficient heterogeneous silver-catalyzed reaction for construction of the α-methylene cyclic carbonate motif was developed through carboxylative assembly of propargyl alcohols and CO2. Such a CO2 fixation protocol proceeded smoothly with only 1 mol% of Ag2WO4 and 2 mol% of PPh3 as well as atmospheric CO2 at room temperature under solvent-free conditions, in an environmentally benign and low energy manner along with an easy operating procedure. Notably, up to 98% isolated yields of carbonates could be attained with exclusive chemo-selectivity. In addition, the dual activation capacity of Ag2WO4 towards both the propargylic substrate and CO2 is based on which cooperative catalytic mechanism by the silver cation and the tungstate anion is proposed. Recycling trials on carboxylative cyclization of propargyl alcohols and CO2 illustrate that the catalyst can be reused at least 4 times with retention of high catalytic activity and selectivity. Especially, it allows the direct and effective application in the one-pot synthesis of various oxazolidinones bearing exocyclic alkenes and carbamates in moderate to high yields upon the alternative introduction of primary or secondary amines." @default.
- W2116965144 created "2016-06-24" @default.
- W2116965144 creator A5003309450 @default.
- W2116965144 creator A5012624234 @default.
- W2116965144 creator A5027233632 @default.
- W2116965144 creator A5036311344 @default.
- W2116965144 creator A5037482835 @default.
- W2116965144 creator A5038396503 @default.
- W2116965144 creator A5053215726 @default.
- W2116965144 creator A5091367597 @default.
- W2116965144 date "2014-01-01" @default.
- W2116965144 modified "2023-10-16" @default.
- W2116965144 title "Efficient chemical fixation of CO2 promoted by a bifunctional Ag2WO4/Ph3P system" @default.
- W2116965144 cites W1966554660 @default.
- W2116965144 cites W1968973827 @default.
- W2116965144 cites W1970973469 @default.
- W2116965144 cites W1972246114 @default.
- W2116965144 cites W1976209408 @default.
- W2116965144 cites W1980008367 @default.
- W2116965144 cites W1990020617 @default.
- W2116965144 cites W1993868948 @default.
- W2116965144 cites W1999631207 @default.
- W2116965144 cites W2003135711 @default.
- W2116965144 cites W2011785644 @default.
- W2116965144 cites W2011887848 @default.
- W2116965144 cites W2016184770 @default.
- W2116965144 cites W2019225864 @default.
- W2116965144 cites W2032921321 @default.
- W2116965144 cites W2035982679 @default.
- W2116965144 cites W2038707175 @default.
- W2116965144 cites W2043224199 @default.
- W2116965144 cites W2045852818 @default.
- W2116965144 cites W2046531710 @default.
- W2116965144 cites W2047182876 @default.
- W2116965144 cites W2047584449 @default.
- W2116965144 cites W2053056806 @default.
- W2116965144 cites W2054148603 @default.
- W2116965144 cites W2056390689 @default.
- W2116965144 cites W2058161479 @default.
- W2116965144 cites W2065620747 @default.
- W2116965144 cites W2069451255 @default.
- W2116965144 cites W2078527804 @default.
- W2116965144 cites W2087495253 @default.
- W2116965144 cites W2088861489 @default.
- W2116965144 cites W2096042571 @default.
- W2116965144 cites W2096388364 @default.
- W2116965144 cites W2103453232 @default.
- W2116965144 cites W2117628261 @default.
- W2116965144 cites W2129773568 @default.
- W2116965144 cites W2145158277 @default.
- W2116965144 cites W2148002316 @default.
- W2116965144 cites W2151278898 @default.
- W2116965144 cites W2154304209 @default.
- W2116965144 cites W2159459560 @default.
- W2116965144 cites W2165742515 @default.
- W2116965144 cites W2168076350 @default.
- W2116965144 cites W2171836549 @default.
- W2116965144 cites W2174759059 @default.
- W2116965144 cites W2314200422 @default.
- W2116965144 cites W2317007725 @default.
- W2116965144 cites W2329605397 @default.
- W2116965144 cites W2950313305 @default.
- W2116965144 cites W2950333329 @default.
- W2116965144 cites W2950814966 @default.
- W2116965144 cites W2952419135 @default.
- W2116965144 cites W2953016096 @default.
- W2116965144 doi "https://doi.org/10.1039/c3gc42406e" @default.
- W2116965144 hasPublicationYear "2014" @default.
- W2116965144 type Work @default.
- W2116965144 sameAs 2116965144 @default.
- W2116965144 citedByCount "173" @default.
- W2116965144 countsByYear W21169651442014 @default.
- W2116965144 countsByYear W21169651442015 @default.
- W2116965144 countsByYear W21169651442016 @default.
- W2116965144 countsByYear W21169651442017 @default.
- W2116965144 countsByYear W21169651442018 @default.
- W2116965144 countsByYear W21169651442019 @default.
- W2116965144 countsByYear W21169651442020 @default.
- W2116965144 countsByYear W21169651442021 @default.
- W2116965144 countsByYear W21169651442022 @default.
- W2116965144 countsByYear W21169651442023 @default.
- W2116965144 crossrefType "journal-article" @default.
- W2116965144 hasAuthorship W2116965144A5003309450 @default.
- W2116965144 hasAuthorship W2116965144A5012624234 @default.
- W2116965144 hasAuthorship W2116965144A5027233632 @default.
- W2116965144 hasAuthorship W2116965144A5036311344 @default.
- W2116965144 hasAuthorship W2116965144A5037482835 @default.
- W2116965144 hasAuthorship W2116965144A5038396503 @default.
- W2116965144 hasAuthorship W2116965144A5053215726 @default.
- W2116965144 hasAuthorship W2116965144A5091367597 @default.
- W2116965144 hasConcept C118792377 @default.
- W2116965144 hasConcept C161790260 @default.
- W2116965144 hasConcept C178790620 @default.
- W2116965144 hasConcept C185592680 @default.
- W2116965144 hasConcept C199873434 @default.
- W2116965144 hasConcept C21951064 @default.
- W2116965144 hasConcept C2778648569 @default.
- W2116965144 hasConcept C2780437523 @default.