Matches in SemOpenAlex for { <https://semopenalex.org/work/W2117145375> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2117145375 endingPage "3621" @default.
- W2117145375 startingPage "3610" @default.
- W2117145375 abstract "‘Hot’ and ‘ cold’ beam chemiluminescence excitation functions have been determined for the Mn + O2 reaction in the 560–700 nm (‘red ’) and 770–900 nm (‘IR ’) regions. While the former is the well-known MnO A6Σ+ → X6Σ+ band system, the latter is identified, by ab initio calculations and the observed alignment, as a new lower-lying A′6Π → X 6Σ+ system. Analysis of the excitation functions by the multiple line-of-centres approach indicates that Mn*(a4DJ) atoms react ia two distinct potential surfaces to yield both MnO* emitting states in common processes. A more excited metastable state also generates products, but the lower z8PJ state yields A 6Σ+ chemiluminescence only. The product rotational alignments 〈P2( ĵ′·)〉 in the higher-threshold processes are initially high, reflecting a line-of-normals energy dependence in which the relative velocity k lies at first in the Mn–O–O plane. For a4DJ atoms, the initial A′6Π alignment is lower than that of A6Σ+, suggesting that the former requires either near-linear or C2v geometry, and the latter less restricted configurations, on the same potential surface." @default.
- W2117145375 created "2016-06-24" @default.
- W2117145375 creator A5006186004 @default.
- W2117145375 creator A5046312052 @default.
- W2117145375 creator A5054101827 @default.
- W2117145375 date "2001-01-01" @default.
- W2117145375 modified "2023-10-16" @default.
- W2117145375 title "Chemiluminescence and rotational alignment in Mn+O2: Direct observation of the MnO*(A′ 6Π) state" @default.
- W2117145375 cites W1589349827 @default.
- W2117145375 cites W1843057816 @default.
- W2117145375 cites W1968099325 @default.
- W2117145375 cites W1981303285 @default.
- W2117145375 cites W1982981192 @default.
- W2117145375 cites W1987155066 @default.
- W2117145375 cites W1990028763 @default.
- W2117145375 cites W2008571474 @default.
- W2117145375 cites W2016607325 @default.
- W2117145375 cites W2021399437 @default.
- W2117145375 cites W2034176028 @default.
- W2117145375 cites W2054407969 @default.
- W2117145375 cites W2057180745 @default.
- W2117145375 cites W2057398628 @default.
- W2117145375 cites W2063663126 @default.
- W2117145375 cites W2068228867 @default.
- W2117145375 cites W2069197437 @default.
- W2117145375 cites W2073775346 @default.
- W2117145375 cites W2077523835 @default.
- W2117145375 cites W2083776016 @default.
- W2117145375 cites W2087733894 @default.
- W2117145375 cites W2105553823 @default.
- W2117145375 cites W2162025056 @default.
- W2117145375 cites W71853975 @default.
- W2117145375 doi "https://doi.org/10.1039/b102508m" @default.
- W2117145375 hasPublicationYear "2001" @default.
- W2117145375 type Work @default.
- W2117145375 sameAs 2117145375 @default.
- W2117145375 citedByCount "5" @default.
- W2117145375 crossrefType "journal-article" @default.
- W2117145375 hasAuthorship W2117145375A5006186004 @default.
- W2117145375 hasAuthorship W2117145375A5046312052 @default.
- W2117145375 hasAuthorship W2117145375A5054101827 @default.
- W2117145375 hasConcept C121332964 @default.
- W2117145375 hasConcept C134121241 @default.
- W2117145375 hasConcept C145802702 @default.
- W2117145375 hasConcept C147789679 @default.
- W2117145375 hasConcept C178790620 @default.
- W2117145375 hasConcept C181500209 @default.
- W2117145375 hasConcept C184779094 @default.
- W2117145375 hasConcept C185592680 @default.
- W2117145375 hasConcept C191897082 @default.
- W2117145375 hasConcept C192562407 @default.
- W2117145375 hasConcept C198352243 @default.
- W2117145375 hasConcept C2524010 @default.
- W2117145375 hasConcept C2781442258 @default.
- W2117145375 hasConcept C33923547 @default.
- W2117145375 hasConcept C41999313 @default.
- W2117145375 hasConcept C528890316 @default.
- W2117145375 hasConcept C62520636 @default.
- W2117145375 hasConcept C83581075 @default.
- W2117145375 hasConcept C89464430 @default.
- W2117145375 hasConceptScore W2117145375C121332964 @default.
- W2117145375 hasConceptScore W2117145375C134121241 @default.
- W2117145375 hasConceptScore W2117145375C145802702 @default.
- W2117145375 hasConceptScore W2117145375C147789679 @default.
- W2117145375 hasConceptScore W2117145375C178790620 @default.
- W2117145375 hasConceptScore W2117145375C181500209 @default.
- W2117145375 hasConceptScore W2117145375C184779094 @default.
- W2117145375 hasConceptScore W2117145375C185592680 @default.
- W2117145375 hasConceptScore W2117145375C191897082 @default.
- W2117145375 hasConceptScore W2117145375C192562407 @default.
- W2117145375 hasConceptScore W2117145375C198352243 @default.
- W2117145375 hasConceptScore W2117145375C2524010 @default.
- W2117145375 hasConceptScore W2117145375C2781442258 @default.
- W2117145375 hasConceptScore W2117145375C33923547 @default.
- W2117145375 hasConceptScore W2117145375C41999313 @default.
- W2117145375 hasConceptScore W2117145375C528890316 @default.
- W2117145375 hasConceptScore W2117145375C62520636 @default.
- W2117145375 hasConceptScore W2117145375C83581075 @default.
- W2117145375 hasConceptScore W2117145375C89464430 @default.
- W2117145375 hasIssue "17" @default.
- W2117145375 hasLocation W21171453751 @default.
- W2117145375 hasOpenAccess W2117145375 @default.
- W2117145375 hasPrimaryLocation W21171453751 @default.
- W2117145375 hasRelatedWork W1976266756 @default.
- W2117145375 hasRelatedWork W2013989409 @default.
- W2117145375 hasRelatedWork W2031570644 @default.
- W2117145375 hasRelatedWork W2036639385 @default.
- W2117145375 hasRelatedWork W2071196734 @default.
- W2117145375 hasRelatedWork W2071322421 @default.
- W2117145375 hasRelatedWork W2076376180 @default.
- W2117145375 hasRelatedWork W2317165715 @default.
- W2117145375 hasRelatedWork W234467752 @default.
- W2117145375 hasRelatedWork W4253889396 @default.
- W2117145375 hasVolume "3" @default.
- W2117145375 isParatext "false" @default.
- W2117145375 isRetracted "false" @default.
- W2117145375 magId "2117145375" @default.
- W2117145375 workType "article" @default.