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- W2117221431 abstract "The electrochemical reduction of 1,4-benzoquinone (Q) in the presence of 1-octylthymine and 9-octyladenine has been performed in dimethylsulfoxide on glassy carbon electrodes. The electrochemical behaviour shows that the semiquinone (Q − ) and the quinone dianion (Q 2− ) interact with 1-octylthymine (TH) following a mechanism which involves association and protonation reactions. It is demonstrated by cyclic voltammetry and NMR experiments, that the protonated dianion (QH − ) is stabilised by an excess of TH, alternatively it disproportionates into an association complex of dianion-hydroquinone [Q,QH 2 ] 2− . The 1-octylthymine anion (T − ) produced in the proton transfer reactions activates a homogeneous chain mechanism allowing the consumption of benzoquinone. For the experiments carried out in the presence of 9-octyladenine (AH), it was observed that only a strong hydrogen bonding association takes place between the nucleobase and Q 2− ." @default.
- W2117221431 created "2016-06-24" @default.
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- W2117221431 date "2003-02-01" @default.
- W2117221431 modified "2023-09-23" @default.
- W2117221431 title "Electrochemical reduction of 1,4-benzoquinone. Interaction with alkylated thymine and adenine nucleobases" @default.
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- W2117221431 doi "https://doi.org/10.1016/s0022-0728(02)01483-3" @default.
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