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- W2117319223 endingPage "6541" @default.
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- W2117319223 abstract "The reaction of the dinuclear cobalt compound [(CpCoS2C2B10H10)(CpCoSC2B10H11)(n-C4H9S)] (1) with HCCC(O)Fc leads to the cobalt-free products (C2B10H10)(SCHCHCOFc)2 (4–6), (S2C2B10H10)(HCCCOFc) (7), and (C2B10H11)(SCHCHCOFc) (8, 9). 4–6 are produced by hydrosulfuration of the alkyne at the 1,2-dicarba-closo-dodecaborane-dithiolate ligand with the generated vinyl groups in Z/Z, Z/E and E/E configurations, respectively. In 7, the alkyne is added to 1,2-dicarba-closo-dodecaborane-dithiolate at the two sulfur sites. 8 and 9 are the products of alkyne hydrosulfuration at the 1,2-dicarba-closo-dodecaborane-1-monothiolate ligand with the generated vinyl group in either Z or E configuration. The treatment of 1 with HCCCO2Me gives rise to the parallel products (C2B10H10)(SCHCHCO2Me)2 (10–12) and (C2B10H11)(SCHCHCO2Me) (13, 14). All of the new compounds have been characterized by IR, NMR, elemental analysis and mass spectroscopy. The structures of compounds 4, 7, and 8 have also been determined by single-crystal X-ray diffraction analysis." @default.
- W2117319223 created "2016-06-24" @default.
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- W2117319223 date "2011-01-01" @default.
- W2117319223 modified "2023-09-23" @default.
- W2117319223 title "Disulfuration and hydrosulfuration of an alkyne at a 1,2-dicarba-closo-dodecaborane-thiolate ligand" @default.
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- W2117319223 doi "https://doi.org/10.1039/c1dt10315f" @default.
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