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• W2117429659 abstract "In this paper, a series of Eu(III) complexes based on four diamine ligands and two diketone ligands were synthesized. Their single crystal structures were studied, where intermolecular π–π stacking was found. The photophysical parameters of these Eu(III) complexes were measured, along with their ligand triplet levels. The energy transfer mechanism between ligand and metal center was discussed in detail. Energy transfer roll-back was found in Eu(III) complexes owing large-conjugated diamine ligands, compromising emissive performance. This energy transfer roll-back, however, could be stopped by the presence of AcO anion, leading to Eu(III) complex emission enhancement. The sensing performance of such Eu(III) complexes was thus investigated in detail. High sensitivity and selectivity were observed." @default.
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• W2117429659 date "2014-06-01" @default.
• W2117429659 modified "2023-10-18" @default.
• W2117429659 title "Emission “Off–On” effect from europium complexes triggered by AcO anion: Synthesis, characterization and sensing performance" @default.
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• W2117429659 doi "https://doi.org/10.1016/j.saa.2014.02.042" @default.
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