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- W2117454916 abstract "A ligand makes a big difference: The 1,3-lithium shift of propargyl/1,2-allenyl lithium has been tuned and applied in a subsequent transmetalation and Pd-catalyzed Negishi coupling reaction with 3-iodoalk-2-enoates to give a highly regioselective and regiodivergent synthesis of 2,4,5-trienoates. It was discovered that ligands play a very important role in the cross-coupling reactions with respect to both regioselectivity and reactivity." @default.
- W2117454916 created "2016-06-24" @default.
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- W2117454916 date "2010-01-04" @default.
- W2117454916 modified "2023-10-16" @default.
- W2117454916 title "Ligand Effects on the Pd-Catalyzed Cross-Coupling Reaction of 3-Iodoalk-2-enoates with Propargyl/1,2-Allenylic Metallic Species: An Efficient Regiodivergent Synthesis of 2,4,5-Trienoates" @default.
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- W2117454916 doi "https://doi.org/10.1002/chem.200901287" @default.
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