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• W2117526672 abstract "Poly(acrylonitrile) films were deposited electrochemically onto vitreous carbon electrodes from air-saturated acrylonitrile. Electrodeposition on gold was investigated with the use of an electrochemical quartz crystal microbalance (EQCM). It was found that the onset of deposition coincided with the reduction of dissolved oxygen at the electrode surface, indicating that the polymerisation reaction is initiated by the nucleophilic superoxide anion. The chemical composition of the film was confirmed by Raman spectroscopy. Such electrodeposited polymer films may have applications as polymer electrolytes for 3D microbattery applications." @default.
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• W2117526672 date "2013-04-01" @default.
• W2117526672 modified "2023-10-17" @default.
• W2117526672 title "An electrochemical quartz crystal microbalance study of poly(acrylonitrile) deposition initiated by electrogenerated superoxide" @default.
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• W2117526672 doi "https://doi.org/10.1016/j.electacta.2013.02.084" @default.
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