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- W2117584206 abstract "Abstract Partial labeling by deuterium may be quantified through simple integrations of those 1 H (200 or 400 MHz ) and 13 C (100.6 MHz ) NMR resonances that are split into pairs by chemical shifts n Δ= δ (deuterated)− δ (nondeuterated) as induced by deuterium across n >2 chemical bonds. The relative intensities of the two components of a pair are shown to be influenced to practically equal degrees by relaxation effects, so that a deuterium fraction may be determined from 1 H and 13 C integral pairs at more remote molecular positions under the routine conditions of fast accumulative spectral acquisition." @default.
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- W2117584206 date "2012-05-08" @default.
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- W2117584206 title "Deuterium Quantification through Deuterium-Induced Remote1H and13C NMR Shifts" @default.
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- W2117584206 doi "https://doi.org/10.1002/chem.201102865" @default.
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