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- W2117658636 abstract "In order to evaluate the effect of Co on the structural stability of , Co-doped samples were synthesized by coprecipitation method. The structural instability, electrochemical properties, reactivity with electrolyte, and thermal stability of the were investigated. Co-substituted (, 0.025, 0.05) showed increase of the specific discharge capacity and improved rate capability compared to . However, X-ray diffraction study of (charged at ) showed that Co substitution increases the lattice parameter in the axis dramatically, compared to the Co undoped electrode . Electron diffraction analysis confirmed that cobalt substitution induced significant structural transformation during cycling in the high-potential range . Furthermore, increase of Co amount in the accelerated Co dissolution at high-temperature storage. The shift of onset temperature of exothermic reaction on differential scanning calorimetric behaviors of the Co-substituted ( and ) was observed." @default.
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- W2117658636 date "2007-01-01" @default.
- W2117658636 modified "2023-10-16" @default.
- W2117658636 title "Structural Transformation of Li[Ni[sub 0.5−x]Co[sub 2x]Mn[sub 0.5−x]]O[sub 2] (2x≤0.1) Charged in High-Voltage Range (4.5 V)" @default.
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- W2117658636 doi "https://doi.org/10.1149/1.2719627" @default.
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