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- W2117739003 abstract "Nanocomposites of two-dimensional (2D) inorganic nanosheets and inorganic nanocrystals are fabricated. Freestanding atomically flat γ-AlOOH nanosheets (thickness <1 nm) are synthesized from a one-pot hydrothermal reaction. The freestanding and binder-free film composed of the γ-AlOOH nanosheets is fabricated by sedimentation. Because they have positive zeta potentials in the pH range below ca. 9.3, the γ-AlOOH nanosheets can function as positively charged 2D inorganic matrices in a broad pH range. By solution phase (pH 7.0) mixing of the γ-AlOOH nanosheets (zeta potential: 30.7 ± 0.8 mV) and inorganic nanocrystals with negative surface charge, including Au nanoparticles, Au nanorods, CdSe quantum dots, CdSe/CdS/ZnS quantum dots and CdSe nanorods, the nanocomposites are self-assembled via electrostatic interactions. Negatively charged inorganic nanostructures with a wide range of chemical compositions, shapes, sizes, surface ligands and adsorbates can be used as building blocks for γ-AlOOH nanocomposites. Adsorption densities of inorganic nanocrystals on the nanocomposites can be controlled by varying concentrations of nanocrystal solutions. Nanocomposite films containing alternating layers of γ-AlOOH and nanocrystals are obtained by a simple drop casting method." @default.
- W2117739003 created "2016-06-24" @default.
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- W2117739003 date "2013-01-01" @default.
- W2117739003 modified "2023-09-26" @default.
- W2117739003 title "Facile fabrication of two-dimensional inorganic nanostructures and their conjugation to nanocrystals" @default.
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- W2117739003 doi "https://doi.org/10.1039/c3tc30756e" @default.
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