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- W2117813571 abstract "Lanthanide ions are strong Lewis acids. Their complexation to a variety of ligands can further enhance their Lewis acidity allowing the hydrolysis of phosphoesters and even DNA. We show that the interaction of lanthanide ions with vesicles from zwitterionic phosphatidylcholine lipids gives supramolecular structures in which the metal ion is loosely coordinated to the surface. This assembly provides a high density of Lewis-acidic metal centres, which hydrolyze phosphodiesters with enhanced rates." @default.
- W2117813571 created "2016-06-24" @default.
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- W2117813571 date "2015-01-01" @default.
- W2117813571 modified "2023-10-13" @default.
- W2117813571 title "The interface makes a difference: lanthanide ion coated vesicles hydrolyze phosphodiesters" @default.
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- W2117813571 doi "https://doi.org/10.1039/c5ob01265a" @default.
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