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- W2117895416 abstract "Abstract These molecular crystals are composed of a structure of S 8 rings. Specimens have been grown from solution in CS 2 both in a thin platelet habit and in the form of thicker double pyramids. Drift mobility techniques have been used to study the charge transport between 180°K and 370°K. This makes it possible to isolate the parameters associated with the transport and distinguish them from those connected with the carrier generation. The results show that the charge is carried by the generated holes having a room temperature lattice mobility of about 10 cm 2 sec −I V −1 and a lifetime of 10 −5 sec. At the lower temperatures the hole drift mobility is an activated process, and during transit the generated holes interact with a level of centres 0.19 eV above the valence band. With increasing temperature a transition to a lattice controlled transport takes place. On the basis of the infra-red transmission spectrum it is suggested that the above centres are associated with solvent molecules. Electron life times are estimated to be shorter than 5 × 10 −9 sec; a predominant electron trap is situated 0·94 eV below the conduction band." @default.
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- W2117895416 date "1964-10-01" @default.
- W2117895416 modified "2023-09-25" @default.
- W2117895416 title "The charge transport in orthorhombic sulphur crystals" @default.
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- W2117895416 doi "https://doi.org/10.1016/0022-3697(64)90134-9" @default.
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