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- W2117918518 abstract "Some characteristics of selected laser dyes are reviewed, and the effect of heterocyclic atom substitutions on triplet (π, π*) transitions is studied experimentally. Specifically, the intensities (oscillator strengths f) of the lowest-energy singlet–singlet (S–S) and triplet–triplet (T–T) transitions of anthracene and some of its heterocyclic analogs were measured. It is shown that this type of substitution of carbon atoms by heteroatoms results in a considerable reduction of intensity of T–T transitions. This observation is important to laser dye technology. The effect is explained by the existence of an efficient vibronic coupling mechanism between (n, π*) and (π, π*) triplet states in heteroatom molecules. Some general guidelines for how to find efficient laser dyes are proposed." @default.
- W2117918518 created "2016-06-24" @default.
- W2117918518 creator A5087432911 @default.
- W2117918518 date "1997-07-20" @default.
- W2117918518 modified "2023-10-03" @default.
- W2117918518 title "Spectroscopy and molecular structure of efficient laser dyes: vibronic spin-orbit interactions in heterocyclics" @default.
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- W2117918518 doi "https://doi.org/10.1364/ao.36.004969" @default.
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