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• W2117967370 abstract "In the title polymer, {[Cu(C8H12N2O6P2)]·2H2O}n, the geometry of the five-coordinate CuII ion can best be described as slightly distorted square-pyramidal formed by one N and two O atoms of an N(CH2PO3H)2 group and one N atom from a pyridine ring. The elongated apex of the pyramid is occupied by one O atom from a third diphospho­nate ligand. The inter­connection of Cu2+ ions by the diphospho­nate ligands results in the formation of a double-chain array along the b axis, in which the two sub-chains are inter­locked by pairs of PO3 groups. The outside of each sub-chain is decorated by other PO3 groups. These double chains are further assembled into a three-dimensional supra­molecular architecture via a large number of O—H⋯O hydrogen bonds between the phospho­nate groups and lattice water mol­ecules." @default.
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• W2117967370 date "2011-12-10" @default.
• W2117967370 modified "2023-10-18" @default.
• W2117967370 title "Poly[[{μ₃-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ⁵<i>O</i>:<i>O</i>′,<i>N</i>,<i>O</i>′′:<i>N</i>′}copper(II)] dihydrate]" @default.
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• W2117967370 doi "https://doi.org/10.1107/s1600536811052512" @default.
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