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- W2117978900 abstract "Abstract Atom transfer radical addition (ATRA) of 2‐chlorodithiane onto aryl alkynes through the use of di‐ tert ‐butyl peroxide as an oxidant at room temperature directly affords a variety of synthetically valuable β‐chloro‐( Z )‐vinyl dithianes in good yields with high regioselectivities and without the assistance of any transition metals. It provides an operationally simple pathway to access vinyl dithianes with controlled formation of a new C(sp 2 )C bond and a C(sp 2 )Cl bond." @default.
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- W2117978900 date "2015-08-21" @default.
- W2117978900 modified "2023-10-12" @default.
- W2117978900 title "Di-<i>tert</i>-Butyl Peroxide-Mediated Atom-Transfer Radical Addition of 2-Chlorodithiane to Aryl Alkynes under Mild Conditions" @default.
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- W2117978900 doi "https://doi.org/10.1002/chem.201502581" @default.
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