FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2118056876> ?p ?o ?g. }

• W2118056876 endingPage "2108" @default.
• W2118056876 startingPage "2102" @default.
• W2118056876 abstract "Nuclear magnetic resonance (NMR) spectroscopy is frequently used in the monitoring of reaction kinetics, due to its nondestructive nature and to the wealth of chemical information that can be obtained. However, when spectra of different mixture components overlap, as is common, the information available is greatly reduced, sometimes to the point where the identification of individual chemical species is not possible. In such cases, the resolution of component spectra and their concentration timecourses can be greatly improved by recording DOSY (diffusion-ordered spectroscopy) data for each time point during the reaction. Adding this additional degree of freedom to the experimental data, allowing the signals of different species to be distinguished through their different rates of diffusion, makes the data trilinear and, therefore, susceptible to analysis by powerful multiway (here, more specifically multilinear) model-free decomposition methods such as PARAFAC (parallel factor analysis). This approach is shown to produce high quality data even for species with near-degenerate spectra. Another important limitation of NMR is its inherently low sensitivity. Here, we show that the combination of DOSY and PARAFAC is surprisingly robust with respect to input data with low signal-to-noise ratio. High quality component spectra and kinetic profiles are obtained from a data set in which the signal-to-noise ratios of the reaction components in the spectra for individual time points are below the detection level." @default.
• W2118056876 created "2016-06-24" @default.
• W2118056876 creator A5002023162 @default.
• W2118056876 creator A5013055575 @default.
• W2118056876 creator A5025694125 @default.
• W2118056876 creator A5026865971 @default.
• W2118056876 creator A5044084759 @default.
• W2118056876 date "2010-02-04" @default.
• W2118056876 modified "2023-09-23" @default.
• W2118056876 title "Reaction Kinetics Studied Using Diffusion-Ordered Spectroscopy and Multiway Chemometrics" @default.
• W2118056876 cites W1528375343 @default.
• W2118056876 cites W1974403130 @default.
• W2118056876 cites W1980913293 @default.
• W2118056876 cites W1981306507 @default.
• W2118056876 cites W1984068166 @default.
• W2118056876 cites W1986888115 @default.
• W2118056876 cites W1988192916 @default.
• W2118056876 cites W1993248390 @default.
• W2118056876 cites W1994522492 @default.
• W2118056876 cites W1998206608 @default.
• W2118056876 cites W1999185695 @default.
• W2118056876 cites W2004080902 @default.
• W2118056876 cites W2005967967 @default.
• W2118056876 cites W2022020757 @default.
• W2118056876 cites W2024074935 @default.
• W2118056876 cites W2025316066 @default.
• W2118056876 cites W2032978589 @default.
• W2118056876 cites W2042901969 @default.
• W2118056876 cites W2047680880 @default.
• W2118056876 cites W2062083462 @default.
• W2118056876 cites W2064292750 @default.
• W2118056876 cites W2065633892 @default.
• W2118056876 cites W2076540020 @default.
• W2118056876 cites W2084761689 @default.
• W2118056876 cites W2099373664 @default.
• W2118056876 cites W2119741678 @default.
• W2118056876 cites W2126063633 @default.
• W2118056876 cites W2129884778 @default.
• W2118056876 cites W2167560742 @default.
• W2118056876 cites W2169752360 @default.
• W2118056876 cites W2490308495 @default.
• W2118056876 cites W2950630380 @default.
• W2118056876 cites W657145799 @default.
• W2118056876 doi "https://doi.org/10.1021/ac100110m" @default.
• W2118056876 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20131871" @default.
• W2118056876 hasPublicationYear "2010" @default.
• W2118056876 type Work @default.
• W2118056876 sameAs 2118056876 @default.
• W2118056876 citedByCount "30" @default.
• W2118056876 countsByYear W21180568762012 @default.
• W2118056876 countsByYear W21180568762013 @default.
• W2118056876 countsByYear W21180568762014 @default.
• W2118056876 countsByYear W21180568762015 @default.
• W2118056876 countsByYear W21180568762016 @default.
• W2118056876 countsByYear W21180568762018 @default.
• W2118056876 countsByYear W21180568762019 @default.
• W2118056876 countsByYear W21180568762020 @default.
• W2118056876 countsByYear W21180568762021 @default.
• W2118056876 countsByYear W21180568762022 @default.
• W2118056876 crossrefType "journal-article" @default.
• W2118056876 hasAuthorship W2118056876A5002023162 @default.
• W2118056876 hasAuthorship W2118056876A5013055575 @default.
• W2118056876 hasAuthorship W2118056876A5025694125 @default.
• W2118056876 hasAuthorship W2118056876A5026865971 @default.
• W2118056876 hasAuthorship W2118056876A5044084759 @default.
• W2118056876 hasConcept C113196181 @default.
• W2118056876 hasConcept C121332964 @default.
• W2118056876 hasConcept C1276947 @default.
• W2118056876 hasConcept C151304367 @default.
• W2118056876 hasConcept C154945302 @default.
• W2118056876 hasConcept C178790620 @default.
• W2118056876 hasConcept C185592680 @default.
• W2118056876 hasConcept C186060115 @default.
• W2118056876 hasConcept C27438332 @default.
• W2118056876 hasConcept C32891209 @default.
• W2118056876 hasConcept C41008148 @default.
• W2118056876 hasConcept C43617362 @default.
• W2118056876 hasConcept C4839761 @default.
• W2118056876 hasConcept C57687973 @default.
• W2118056876 hasConcept C62520636 @default.
• W2118056876 hasConcept C69357855 @default.
• W2118056876 hasConcept C86803240 @default.
• W2118056876 hasConcept C97355855 @default.
• W2118056876 hasConceptScore W2118056876C113196181 @default.
• W2118056876 hasConceptScore W2118056876C121332964 @default.
• W2118056876 hasConceptScore W2118056876C1276947 @default.
• W2118056876 hasConceptScore W2118056876C151304367 @default.
• W2118056876 hasConceptScore W2118056876C154945302 @default.
• W2118056876 hasConceptScore W2118056876C178790620 @default.
• W2118056876 hasConceptScore W2118056876C185592680 @default.
• W2118056876 hasConceptScore W2118056876C186060115 @default.
• W2118056876 hasConceptScore W2118056876C27438332 @default.
• W2118056876 hasConceptScore W2118056876C32891209 @default.
• W2118056876 hasConceptScore W2118056876C41008148 @default.
• W2118056876 hasConceptScore W2118056876C43617362 @default.
• W2118056876 hasConceptScore W2118056876C4839761 @default.
• W2118056876 hasConceptScore W2118056876C57687973 @default.
• W2118056876 hasConceptScore W2118056876C62520636 @default.

• next