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- W2118067400 abstract "The relation of the straightforward Rayleigh-Schrödinger perturbation theory for the interaction of two atoms to the asymptotic exchange theory is described. The one-electron case of a hydrogen atom perturbed by a nucleus is examined in detail. It is shown that the asymptotic theory contains an infinite summation of terms in the Rayleigh-Schrödinger series. The nature of the branching between states and its implications for convergence is elucidated." @default.
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- W2118067400 date "1976-01-01" @default.
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- W2118067400 title "The relationship between the Rayleigh-Schrödinger and asymptotic perturbation theories of intermolecular forces" @default.
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- W2118067400 doi "https://doi.org/10.1002/qua.560100107" @default.
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