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• W2118082167 abstract "Abstract A regioselective synthesis of unsymmetrical biaryls with electron withdrawing or donating substituents is described and illustrated by carbanion-induced ring transformation of 6-aryl-α-pyrones with methoxyacetone in excellent yield. Our methodology is an alternative to classical organometal-catalyzed aryl–aryl coupling reactions and can be applied to the synthesis of functionally demanding naphthyl biaryls for the development of new ligands for asymmetric synthesis." @default.
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• W2118082167 date "2007-10-01" @default.
• W2118082167 modified "2023-09-23" @default.
• W2118082167 title "A regioselective palladium-free protocol for accessing unsymmetrical biaryls through ring transformation of 6-aryl-α-pyrones" @default.
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• W2118082167 doi "https://doi.org/10.1016/j.tetlet.2007.08.051" @default.
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