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- W2118152923 abstract "InIOTf has been uncovered as an effective Lewis acid catalyst for unprecedented nucleophilic substitution of acetals or ketals with allylboronates. A transmetalative SN1 mechanism is proposed in which a single InI center acts as a dual catalyst to activate both reagents sequentially. Contrary to the classic γ-selectivity of allylsilanes (Hosomi−Sakurai reaction), this InI-catalyzed borono variant displays distinct α-selectivity. Substrate scope and functional group tolerance proved to be excellent." @default.
- W2118152923 created "2016-06-24" @default.
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- W2118152923 date "2010-05-12" @default.
- W2118152923 modified "2023-10-16" @default.
- W2118152923 title "Unusual Carbon−Carbon Bond Formations between Allylboronates and Acetals or Ketals Catalyzed by a Peculiar Indium(I) Lewis Acid" @default.
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- W2118152923 doi "https://doi.org/10.1021/ol100450s" @default.
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