FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2118222011> ?p ?o ?g. }

• W2118222011 endingPage "6738" @default.
• W2118222011 startingPage "6724" @default.
• W2118222011 abstract "Abstract A detailed mechanistic study of the hydroxylation of alkane CH bonds using H 2 O 2 by a family of mononuclear non heme iron catalysts with the formula [Fe II (CF 3 SO 3 ) 2 (L)] is described, in which L is a tetradentate ligand containing a triazacyclononane tripod and a pyridine ring bearing different substituents at the α and γ positions, which tune the electronic or steric properties of the corresponding iron complexes. Two inequivalent cis ‐labile exchangeable sites, occupied by triflate ions, complete the octahedral iron coordination sphere. The CH hydroxylation mediated by this family of complexes takes place with retention of configuration. Oxygen atoms from water are incorporated into hydroxylated products and the extent of this incorporation depends in a systematic manner on the nature of the catalyst, and the substrate. Mechanistic probes and isotopic analyses, in combination with detailed density functional theory (DFT) calculations, provide strong evidence that CH hydroxylation is performed by highly electrophilic [Fe V (O)(OH)L] species through a concerted asynchronous mechanism, involving homolytic breakage of the CH bond, followed by rebound of the hydroxyl ligand. The [Fe V (O)(OH)L] species can exist in two tautomeric forms, differing in the position of oxo and hydroxide ligands. Isotopic‐labeling analysis shows that the relative reactivities of the two tautomeric forms are sensitively affected by the α substituent of the pyridine, and this reactivity behavior is rationalized by computational methods." @default.
• W2118222011 created "2016-06-24" @default.
• W2118222011 creator A5008387911 @default.
• W2118222011 creator A5018219458 @default.
• W2118222011 creator A5024836740 @default.
• W2118222011 creator A5026304318 @default.
• W2118222011 creator A5030135017 @default.
• W2118222011 creator A5038561689 @default.
• W2118222011 creator A5087808725 @default.
• W2118222011 date "2013-03-27" @default.
• W2118222011 modified "2023-10-18" @default.
• W2118222011 title "The Mechanism of Stereospecific CH Oxidation by Fe(Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containing<i>cis</i>-Labile Exchangeable Sites" @default.
• W2118222011 cites W1967700647 @default.
• W2118222011 cites W1970522028 @default.
• W2118222011 cites W1972360931 @default.
• W2118222011 cites W1974051298 @default.
• W2118222011 cites W1974842081 @default.
• W2118222011 cites W1975347365 @default.
• W2118222011 cites W1976728390 @default.
• W2118222011 cites W1979061243 @default.
• W2118222011 cites W1979692587 @default.
• W2118222011 cites W1979845823 @default.
• W2118222011 cites W1981763423 @default.
• W2118222011 cites W1983098087 @default.
• W2118222011 cites W1983514748 @default.
• W2118222011 cites W1985935792 @default.
• W2118222011 cites W1986513799 @default.
• W2118222011 cites W1988949059 @default.
• W2118222011 cites W1989269725 @default.
• W2118222011 cites W1994533504 @default.
• W2118222011 cites W2001299931 @default.
• W2118222011 cites W2003278853 @default.
• W2118222011 cites W2005927376 @default.
• W2118222011 cites W2009317764 @default.
• W2118222011 cites W2010230142 @default.
• W2118222011 cites W2012211558 @default.
• W2118222011 cites W2014926653 @default.
• W2118222011 cites W2018473500 @default.
• W2118222011 cites W2019406135 @default.
• W2118222011 cites W2021144578 @default.
• W2118222011 cites W2023558950 @default.
• W2118222011 cites W2025105240 @default.
• W2118222011 cites W2031059348 @default.
• W2118222011 cites W2032753263 @default.
• W2118222011 cites W2034796508 @default.
• W2118222011 cites W2036709714 @default.
• W2118222011 cites W2038700747 @default.
• W2118222011 cites W2039499832 @default.
• W2118222011 cites W2040887561 @default.
• W2118222011 cites W2041936177 @default.
• W2118222011 cites W2049557754 @default.
• W2118222011 cites W2050412574 @default.
• W2118222011 cites W2052808022 @default.
• W2118222011 cites W2054950973 @default.
• W2118222011 cites W2059538067 @default.
• W2118222011 cites W2060296131 @default.
• W2118222011 cites W2062666384 @default.
• W2118222011 cites W2063249326 @default.
• W2118222011 cites W2063913713 @default.
• W2118222011 cites W2064729225 @default.
• W2118222011 cites W2065895273 @default.
• W2118222011 cites W2066023565 @default.
• W2118222011 cites W2069072844 @default.
• W2118222011 cites W2072635052 @default.
• W2118222011 cites W2072648963 @default.
• W2118222011 cites W2073356400 @default.
• W2118222011 cites W2076655264 @default.
• W2118222011 cites W2078567919 @default.
• W2118222011 cites W2079692035 @default.
• W2118222011 cites W2084787090 @default.
• W2118222011 cites W2086940121 @default.
• W2118222011 cites W2087003279 @default.
• W2118222011 cites W2087366412 @default.
• W2118222011 cites W2088976181 @default.
• W2118222011 cites W2089612572 @default.
• W2118222011 cites W2090560403 @default.
• W2118222011 cites W2093219163 @default.
• W2118222011 cites W2094032734 @default.
• W2118222011 cites W2094204173 @default.
• W2118222011 cites W2097712991 @default.
• W2118222011 cites W2099693699 @default.
• W2118222011 cites W2100032379 @default.
• W2118222011 cites W2105200096 @default.
• W2118222011 cites W2106369407 @default.
• W2118222011 cites W2106487454 @default.
• W2118222011 cites W2106953389 @default.
• W2118222011 cites W2111071894 @default.
• W2118222011 cites W2113382690 @default.
• W2118222011 cites W2114780368 @default.
• W2118222011 cites W2117800759 @default.
• W2118222011 cites W2118286718 @default.
• W2118222011 cites W2124408629 @default.
• W2118222011 cites W2125845584 @default.
• W2118222011 cites W2135361855 @default.
• W2118222011 cites W2139399189 @default.
• W2118222011 cites W2140158011 @default.
• W2118222011 cites W2142419145 @default.
• W2118222011 cites W2144860443 @default.

• next