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• W2118300391 abstract "Abstract In order to develop a new class of transition-metal-based, two-stage photobase generators (PBGs), the synthesis, structural characterization, spectroscopic properties and base-generation ability of a series of [CpRu(η6-benzylcarbamate)]X salts (X = [PF6]−, [O3SCF3]−) are reported. Treatment of [CpRu(NCMe)3]PF6 with the N,N-dialkylcarbamate PBGs 2-nitrophenylmethyl N,N-dicyclohexylcarbamate (2NC), 4-nitrophenylmethyl N,N-dicyclohexylcarbamate (4NC) and 3,5-dimethoxyphenylmethyl N,N-dicyclohexylcarbamate (DMC) results in η6-complexation of the arene fragment and formation of the corresponding [CpRu(η6-benzylcarbamate)]PF6 salt. The [PF6]− salt, [CpRu(η6-DMC)]PF6, is converted to the triflate salt (triflate = [O3SCF3]− = [OTf]−) by treatment with Me3SiOTf. The molecular structures of the [CpRu(η6-benzylcarbamate)]X salts were determined by X-ray diffraction and varied by the orientation of the carbmamate unit relative to the η5-Cp ligand. Experimental UV–Vis data and Time-Dependent DFT calculations suggest that the [CpRu(η6-benzylcarbamate)]+ cations possess high-energy excitations that potentially render these salts as useful two-stage PBGs. The photobase generation ability of the [CpRu(η6-benzylcarbamate)]X salts at 254 nm irradiation is assessed in both acetonitrile solution and polymethacrylate thin films. The irradiation studies demonstrate that η6-coordination of a benzylcarbamate PBG does not deactivate photolytic base generation." @default.
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• W2118300391 date "2014-10-01" @default.
• W2118300391 modified "2023-10-06" @default.
• W2118300391 title "Development of [CpRu(η 6 -benzylcarbamate)]X salts as two-stage photobase generators" @default.
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• W2118300391 doi "https://doi.org/10.1016/j.ica.2014.06.033" @default.
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