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• W2118374603 abstract "Cu/SiO 2 catalysts, for the synthesis of ethylene glycol (EG) from hydrogenation of dimethyl oxalate (DMO), were prepared by ammonia-evaporation and sol-gel methods, respectively. The structure, size of copper nanoparticles, copper dispersion, and the surface chemical states were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), temperature-programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS) and N 2 adsorption. It is found the structures and catalytic performances of the catalysts were highly affected by the preparation method. The catalyst prepared by sol-gel method had smaller average size of copper nanoparticles (about 3-4 nm), better copper dispersion, higher Cu + /C 0 ratio and larger BET surface area, and higher DMO conversion and EG selectivity under the optimized reaction conditions." @default.
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• W2118374603 date "2013-01-01" @default.
• W2118374603 modified "2023-09-25" @default.
• W2118374603 title "Effect of Copper Nanoparticles Dispersion on Catalytic Performance of Cu/SiO₂Catalyst for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol" @default.
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• W2118374603 doi "https://doi.org/10.1155/2013/629375" @default.
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