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- W2118492072 abstract "Treatment of TiCl(NMe2)3 with H3N·B(C6F5)3 results in N–H activation and ligand exchange to yield the structurally characterised salt [TiCl(NMe2)2(NMe2H)2]+[TiNB(C6F5)3(Cl)2(NMe2H)2]−. Cation exchange with [Me4N]Cl, [Ph4P]Cl and [(PhCH2)Ph3P]Cl yields the respective ammonium and phosphonium salts of the [TiNB(C6F5)3(Cl)2(NMe2H)2]− anion. X-ray crystallography reveals that the essential trigonal bipyramidal geometry and composition of the anion is retained in each of these salts despite some minor variations in the Ti–N–B angle and the nature of the interionic interactions. Electronic investigation by DFT calculations confirmed the Ti–N triple bond character implied by the experimentally determined bond length, with the HOMO and HOMO-1 having Ti–N π-bonding character. The dimethylamine ligands of the anion resist substitution by moderate bases but can be displaced by pyridine to give a pentacoordinate anion. In contrast, addition of 2,2′-bipyridyl gives a neutral octahedral complex. Treatment of the pyridine complex with TlCp results in the formation of a four coordinate anionic cyclopentadienyl complex." @default.
- W2118492072 created "2016-06-24" @default.
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- W2118492072 date "2012-01-01" @default.
- W2118492072 modified "2023-10-17" @default.
- W2118492072 title "The structure and chemistry of tris(pentafluorophenyl)borane protected mononuclear nitridotitanium complexes" @default.
- W2118492072 cites W1501319738 @default.
- W2118492072 cites W1970743254 @default.
- W2118492072 cites W1971236437 @default.
- W2118492072 cites W1971545461 @default.
- W2118492072 cites W1973345440 @default.
- W2118492072 cites W1974203754 @default.
- W2118492072 cites W1975567652 @default.
- W2118492072 cites W1975959748 @default.
- W2118492072 cites W1983772602 @default.
- W2118492072 cites W1993361210 @default.
- W2118492072 cites W1993625987 @default.
- W2118492072 cites W1994835897 @default.
- W2118492072 cites W1995277252 @default.
- W2118492072 cites W1996555263 @default.
- W2118492072 cites W2007731581 @default.
- W2118492072 cites W2007787107 @default.
- W2118492072 cites W2009289366 @default.
- W2118492072 cites W2012334719 @default.
- W2118492072 cites W2012709454 @default.
- W2118492072 cites W2014160943 @default.
- W2118492072 cites W2015390373 @default.
- W2118492072 cites W2017611936 @default.
- W2118492072 cites W2019266815 @default.
- W2118492072 cites W2026736969 @default.
- W2118492072 cites W2027520555 @default.
- W2118492072 cites W2031245685 @default.
- W2118492072 cites W2034208965 @default.
- W2118492072 cites W2041075391 @default.
- W2118492072 cites W2041173826 @default.
- W2118492072 cites W2041554980 @default.
- W2118492072 cites W2042135160 @default.
- W2118492072 cites W2043943524 @default.
- W2118492072 cites W2045237782 @default.
- W2118492072 cites W2045606380 @default.
- W2118492072 cites W2049104552 @default.
- W2118492072 cites W2049974129 @default.
- W2118492072 cites W2051216832 @default.
- W2118492072 cites W2055174696 @default.
- W2118492072 cites W2056607244 @default.
- W2118492072 cites W2056784313 @default.
- W2118492072 cites W2061076493 @default.
- W2118492072 cites W2063334178 @default.
- W2118492072 cites W2065236211 @default.
- W2118492072 cites W2065528827 @default.
- W2118492072 cites W2066123671 @default.
- W2118492072 cites W2070226595 @default.
- W2118492072 cites W2071450740 @default.
- W2118492072 cites W2081971863 @default.
- W2118492072 cites W2082208930 @default.
- W2118492072 cites W2085109354 @default.
- W2118492072 cites W2085703942 @default.
- W2118492072 cites W2086673711 @default.
- W2118492072 cites W2089496419 @default.
- W2118492072 cites W2091803041 @default.
- W2118492072 cites W2091986312 @default.
- W2118492072 cites W2114317445 @default.
- W2118492072 cites W2122134641 @default.
- W2118492072 cites W2127512983 @default.
- W2118492072 cites W2128179295 @default.
- W2118492072 cites W2128348919 @default.
- W2118492072 cites W2131350133 @default.
- W2118492072 cites W2144566090 @default.
- W2118492072 cites W2151980473 @default.
- W2118492072 cites W2159781292 @default.
- W2118492072 cites W2163902930 @default.
- W2118492072 cites W2265612692 @default.
- W2118492072 cites W2314164364 @default.
- W2118492072 cites W2317841068 @default.
- W2118492072 cites W2326651939 @default.
- W2118492072 cites W2333081378 @default.
- W2118492072 cites W2951013911 @default.
- W2118492072 cites W2952360739 @default.
- W2118492072 cites W4254524944 @default.
- W2118492072 doi "https://doi.org/10.1039/c2dt00056c" @default.
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