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• W2118610080 abstract "Abstract Reaction of equimolar amounts of Cu(OAc) 2 · H 2 O and bis[4‐(3‐ethoxysalicylideneamino)phenyl]methane ( H 2 L 1 ) or bis[4‐(3‐ethoxysalicylideneamino)phenyl]sulfide ( H 2 L 2 ) in a 1:1 THF/MeOH mixture leads to the formation of structure‐analogous Cu II helicates of the composition [{Cu 2 L 2 }(H 2 O) 2 }] · 4H 2 O. The helicates form left‐ and right‐handed hydrogen bonded strands using the bound water molecules as glue. Finally, a compact 3D arrangement of the molecules is achieved by weak π ··· π and CH ··· π interactions. The Cu II ions possess a strongly distorted tetrahedral arrangement with a N 2 O 2 donor set of the involved diimines. In addition, the molecular structure of the ligand H 2 L 2 was determined and solution studies of the complex formation using UV/Vis and ESI‐MS were performed." @default.
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• W2118610080 date "2015-09-07" @default.
• W2118610080 modified "2023-10-17" @default.
• W2118610080 title "Self-assembly of Dinuclear Double-stranded Copper(II) Helicates with 3-Ethoxy-2-hydroxyphenyl Substituted Diimines. Synthesis, Molecular Structure, and Host-guest Recognition of H₂O" @default.
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• W2118610080 doi "https://doi.org/10.1002/zaac.201500547" @default.
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