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- W2118640810 abstract "Herein we report a theoretical study of diode-like behavior of negatively charged (e.g., glass or silica) nanopores at different potential scan rates (1-1000 V·s(-1)). Finite element simulations were used to determine current-voltage characteristics of conical nanopores at various electrolyte concentrations. This study demonstrates that significant changes in rectification behavior can be observed at high scan rates because the mass transport of ionic species appears sluggish on the time scale of the voltage scan. In particular, it explains the influence of the potential scan rate on the nanopore rectifying properties in the cases of classical rectification, rectification inversion, and the transition rectification domain where the rectification direction in the nanopore could be modulated according to the applied scan rate." @default.
- W2118640810 created "2016-06-24" @default.
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- W2118640810 date "2011-08-25" @default.
- W2118640810 modified "2023-09-30" @default.
- W2118640810 title "Scan-Rate-Dependent Ion Current Rectification and Rectification Inversion in Charged Conical Nanopores" @default.
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- W2118640810 doi "https://doi.org/10.1021/ja2048368" @default.
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