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- W2118643681 abstract "Abstract An efficient and highly stereoselective synthetic procedure is reported for the construction of symmetrical and unsymmetrical ( E )‐polymethoxystilbene and ( E )‐polyhydroxystilbene derivatives. The strategy rests on a cross‐metathesis reaction catalyzed by stable, well‐defined (alkylidene)ruthenium complexes, in particular the second‐generation Grubbs catalyst [RuCl 2 (=CHPh)(SIMes)(PCy 3 )] [SIMes = 1,3‐bis(2,4,6‐trimethylphenyl)imidazolidin‐2‐ylidene]. The metathesis of unprotected phenolic styrenes is illustrated by the synthesis of the important phytoalexins ( E )‐3,4',5‐trihydroxystilbene (resveratrol) and ( E )‐3,3',4,5'‐tetrahydroxystilbene(piceatannol). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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- W2118643681 date "2005-07-14" @default.
- W2118643681 modified "2023-10-18" @default.
- W2118643681 title "Stereoselective Synthesis of (<i>E</i>)‐Hydroxystilbenoids by Ruthenium‐Catalyzed Cross‐Metathesis" @default.
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- W2118643681 doi "https://doi.org/10.1002/ejoc.200500068" @default.
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