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- W2118753634 abstract "Complexes of n-tetradecylammonium-beidellite with n-alkanols $${rm{(n - }}{{rm{C}}_{{rm{14}}}}{{rm{H}}_{{rm{29}}}}{rm{N}}{{rm{H}}_{rm{3}}}^{rm{+}}{rm{)_{{rm{0,44}}}(n - C_{{rm{x}}}}}{{rm{H}}_{{rm{2x}}}}{rm{+}}{}_{rm{1}}{rm{OH) }}{}_{{rm{1,56}}}{{rm{{ M}}{{rm{g}}_{{rm{0,28}}}}{rm{A}}{{rm{l}}_{{rm{1,81}}}}{{rm{(OH)}}_{rm{2}}}{rm{S}}{{rm{i}}_{{rm{3,56}}}}{rm{Al}}{}_{{rm{0,44}}}{rm{O_{{10}} }}}^{{rm{0,44 - }}}}$$ (x = 8–22) have been prepared and characterized by their basal spacings and by measurements of the specific heat cp. The compounds undergo a series of reversible phase transitions $${beta _1} rightleftharpoons...rightleftharpoons{beta_i}rightleftharpoons...rightleftharpoons{beta_omega}rightleftharpoons{alpha_1}...rightleftharpoons{alpha_j}$$ with rising temperature. The maximum number ω of β-phases depends upon the chain lengths and increases from 1 with decanol to 6 with docosanol. Due to the evaporation of alkanol the number of χ-phases is not yet established in all details. The β-transitions correspond to conformational changes of the alkyl chains via rotational isomerisation, especially kink formation. The β-phases become unstable if the kink concentration exceeds 0,14 kinks/-CH2-. The β/α-transition is probably caused by a rearrangement into special gauche-block structures." @default.
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- W2118753634 date "1975-01-01" @default.
- W2118753634 modified "2023-10-11" @default.
- W2118753634 title "Kink Block Structures in Clay Organic Complexes" @default.
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- W2118753634 doi "https://doi.org/10.1346/ccmn.1975.0230107" @default.
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