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- W2118859779 abstract "Die nicht explosive Knallsäure ist eine wesentlich stärkere Säure als HCN (pKs ≦ 5;25°); ihre Säurestärke ist vergleichbar mit der von HN3. Die Infrarotspektren von gasförmigem HCNO und DCNO wurden aufgenommen; die Zuordnung der Absorptionen wird durch eine Normalkoordinatenanalyse gestützt. Die Kraftkonstanten des linearen Formonitriloxid-Moleküls HCNO werden mit denen ähnlicher Moleküle verglichen. Die isosteren Verbindungen HCNO und N2O zeigen sehr ähnliche Valenzkraftkonstanten. Properties and Infrared Spectrum of Fulminic Acid, HCNO The non-explosive fulminic acid is a considerably stronger acid than HCN (pKa ≦ 5;25°); its acid strength is similar to that of HN3. Infrared spectra of both HCNO and DCNO in the gas phase were determined: the assignment of the absorption bands is supported by the results of a normal coordinate analysis. The force constants for the linear formonitrile oxide HCNO are compared with those for related liner molecules, and the bonding in HCNO is discussed. The isosteric molecules HCNO and N2O have very similar valence force constants." @default.
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- W2118859779 date "1971-02-01" @default.
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- W2118859779 title "Eigenschaften und IR‐Spektrum der Knallsäure HCNO" @default.
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- W2118859779 doi "https://doi.org/10.1002/cber.19711040223" @default.
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