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- W2118910504 abstract "On the move: Decarboxylative coupling of allyl 4-methyl-3-carboxycoumarins provides the products of γ-allylation of the methyl group rather than the typical regiospecific α-allylation. Mechanistic studies show that intramolecular proton transfer from the 4-methyl group to the 3-carboxylate allows allylation of the remote methyl group. The resulting 4-butenyl-3-carboxyl coumarin undergoes Pd0-catalyzed decarboxylation to provide the observed products (see scheme)." @default.
- W2118910504 created "2016-06-24" @default.
- W2118910504 creator A5018683336 @default.
- W2118910504 creator A5023300512 @default.
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- W2118910504 date "2011-04-19" @default.
- W2118910504 modified "2023-10-18" @default.
- W2118910504 title "Migratory Decarboxylative Coupling of Coumarins: Synthetic and Mechanistic Aspects" @default.
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- W2118910504 doi "https://doi.org/10.1002/anie.201100765" @default.
- W2118910504 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3521504" @default.
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