FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2118935767> ?p ?o ?g. }

• W2118935767 endingPage "2994" @default.
• W2118935767 startingPage "2979" @default.
• W2118935767 abstract "In this contribution we show that host materials based on metal dibenzoylmethanates (DBM) can be extended in a versatile way by decreasing the packing efficiency of the simpler metal DBM's reported earlier. Specifically, this can be accomplished by coordinating two 4-vinylpyridines (4-ViPy) to the metal (Ni or Co) DBM units to give [M(4-ViPy)2(DBM)2] host complexes. These display a remarkable polymorphism and an ability to form inclusion compounds with a large variety of organic species. Five non-clathrate phases representing three polymorphic types and twenty-eight inclusion compounds with nineteen guests representing five structural types were isolated and studied in varying degrees of detail. The inclusion compounds can be prepared by recrystallization or by interaction of the solid host with guest vapor. In the latter case, the process realization, kinetics and final product strongly depend on the host polymorph chosen as starting material. Kinetic studies executed with powder XRD suggest that transient formation of inclusion compounds may occur even during solvent vapor induced transformation of one guest-free polymorph to another. The β polymorph of the Ni-host reveals the strongest clathratogenic ability as well as a high selectivity towards certain homologues and isomers. Its properties give insight into the concept of “flexible zeolite mimics”, or “apohosts”, as this empty host form is energetically and structurally predisposed towards inclusion processes. In all eleven (three host and eight clathrate) structures studied by single crystal X-ray diffraction the [M(4-ViPy)2(DBM)2] complex molecule is trans-configured. In most, the host molecules show effective packing in one dimension by forming parallel chains. Guest species are located between the chains in cages or channels formed by combining voids in the host molecules belonging to adjacent chains. The corresponding Ni and Co versions of the compounds studied were similar." @default.
• W2118935767 created "2016-06-24" @default.
• W2118935767 creator A5052194742 @default.
• W2118935767 creator A5089988046 @default.
• W2118935767 date "2001-07-16" @default.
• W2118935767 modified "2023-10-12" @default.
• W2118935767 title "Novel 4-Vinylpyridine-Extended Metal-Dibenzoylmethanate Host Frameworks: Structure, Polymorphism, and Inclusion Properties" @default.
• W2118935767 cites W1666635286 @default.
• W2118935767 cites W176535488 @default.
• W2118935767 cites W1966323357 @default.
• W2118935767 cites W1970262392 @default.
• W2118935767 cites W1971590970 @default.
• W2118935767 cites W1971733705 @default.
• W2118935767 cites W1977721910 @default.
• W2118935767 cites W1982188676 @default.
• W2118935767 cites W1982479385 @default.
• W2118935767 cites W1986584762 @default.
• W2118935767 cites W1986696172 @default.
• W2118935767 cites W1986899487 @default.
• W2118935767 cites W1987732445 @default.
• W2118935767 cites W1987799315 @default.
• W2118935767 cites W1990372599 @default.
• W2118935767 cites W1991587124 @default.
• W2118935767 cites W1992440411 @default.
• W2118935767 cites W1996065932 @default.
• W2118935767 cites W1998723816 @default.
• W2118935767 cites W2007243707 @default.
• W2118935767 cites W2008925243 @default.
• W2118935767 cites W2010865046 @default.
• W2118935767 cites W2014128072 @default.
• W2118935767 cites W2018630935 @default.
• W2118935767 cites W2018835468 @default.
• W2118935767 cites W2020158064 @default.
• W2118935767 cites W2025826890 @default.
• W2118935767 cites W2027809726 @default.
• W2118935767 cites W2030841140 @default.
• W2118935767 cites W2031068859 @default.
• W2118935767 cites W2031572667 @default.
• W2118935767 cites W2033441963 @default.
• W2118935767 cites W2035231395 @default.
• W2118935767 cites W2036170029 @default.
• W2118935767 cites W2038153074 @default.
• W2118935767 cites W2042685153 @default.
• W2118935767 cites W2043436586 @default.
• W2118935767 cites W2051716740 @default.
• W2118935767 cites W2052010280 @default.
• W2118935767 cites W2059788401 @default.
• W2118935767 cites W2060048911 @default.
• W2118935767 cites W2064550721 @default.
• W2118935767 cites W2064733502 @default.
• W2118935767 cites W2078265928 @default.
• W2118935767 cites W2078410387 @default.
• W2118935767 cites W2080528351 @default.
• W2118935767 cites W2084024682 @default.
• W2118935767 cites W2086941414 @default.
• W2118935767 cites W2092071092 @default.
• W2118935767 cites W2104601299 @default.
• W2118935767 cites W2108280669 @default.
• W2118935767 cites W2110335027 @default.
• W2118935767 cites W2156918663 @default.
• W2118935767 cites W2161816068 @default.
• W2118935767 cites W2334802734 @default.
• W2118935767 cites W2951150801 @default.
• W2118935767 cites W31609241 @default.
• W2118935767 doi "https://doi.org/10.1002/1521-3765(20010716)7:14<2979::aid-chem2979>3.0.co;2-u" @default.
• W2118935767 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11495424" @default.
• W2118935767 hasPublicationYear "2001" @default.
• W2118935767 type Work @default.
• W2118935767 sameAs 2118935767 @default.
• W2118935767 citedByCount "58" @default.
• W2118935767 countsByYear W21189357672013 @default.
• W2118935767 countsByYear W21189357672014 @default.
• W2118935767 countsByYear W21189357672015 @default.
• W2118935767 countsByYear W21189357672016 @default.
• W2118935767 countsByYear W21189357672018 @default.
• W2118935767 countsByYear W21189357672019 @default.
• W2118935767 countsByYear W21189357672020 @default.
• W2118935767 countsByYear W21189357672021 @default.
• W2118935767 crossrefType "journal-article" @default.
• W2118935767 hasAuthorship W2118935767A5052194742 @default.
• W2118935767 hasAuthorship W2118935767A5089988046 @default.
• W2118935767 hasConcept C100402318 @default.
• W2118935767 hasConcept C104317684 @default.
• W2118935767 hasConcept C115624301 @default.
• W2118935767 hasConcept C135763542 @default.
• W2118935767 hasConcept C149737253 @default.
• W2118935767 hasConcept C178790620 @default.
• W2118935767 hasConcept C185592680 @default.
• W2118935767 hasConcept C192562407 @default.
• W2118935767 hasConcept C2781060337 @default.
• W2118935767 hasConcept C32909587 @default.
• W2118935767 hasConcept C544153396 @default.
• W2118935767 hasConcept C55493867 @default.
• W2118935767 hasConcept C71240020 @default.
• W2118935767 hasConcept C73922627 @default.
• W2118935767 hasConcept C8010536 @default.
• W2118935767 hasConceptScore W2118935767C100402318 @default.
• W2118935767 hasConceptScore W2118935767C104317684 @default.

• next