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- W2119041385 abstract "The DABCO-catalyzed divergent (4 + 2) annulations of δ-acetoxy allenoates 1 are reported. The chemical behavior of 1 under DABCO catalyst was found to be substrate dependent. Allenoate 1 with an aromatic group at δC preferentially reacted with salicylaldehyde derivative 2, delivering 4H-chromenes 3. On the other hand, allenoates 1 with an alkyl group at δC readily underwent (4 + 2) annulations with oxo diene 4 to afford 4H-pyrans 5." @default.
- W2119041385 created "2016-06-24" @default.
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- W2119041385 date "2015-02-18" @default.
- W2119041385 modified "2023-10-11" @default.
- W2119041385 title "Tertiary Amine-Catalyzed (4 + 2) Annulations of δ-Acetoxy Allenoates: Synthesis of Multisubstituted 4<i>H</i>-Pyran and 4<i>H</i>-Chromene" @default.
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- W2119041385 doi "https://doi.org/10.1021/acs.orglett.5b00359" @default.
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