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- W2119184978 abstract "Syn- oder Anti-pathie: Die relative Konfiguration eines α-Methylen-γ-butyrolactons 1 kann mithilfe dipolarer Restkopplungen (RDCs) bestimmt werden. Konventionelle NMR-Methoden schlugen fehl, da im Konformationsraum beider Diastereomere Strukturen existieren, die mit den experimentellen NOE-Daten und 3J-Kopplungskonstanten in Einklang sind. Aus Messungen von homo- and heteronuclearen RDCs und Vergleich mit den möglichen Konformeren kann geschlossen werden, dass 1 trans-konfiguriert ist. Hintergrundinformationen zu diesem Beitrag sind im WWW unter http://www.wiley-vch.de/contents/jc_2001/2006/z503247_s.pdf zu finden oder können beim Autor angefordert werden. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2119184978 date "2006-07-03" @default.
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- W2119184978 title "Bestimmung der relativen Konfiguration eines Fünfring-Lactons aus dipolaren Restkopplungen" @default.
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- W2119184978 doi "https://doi.org/10.1002/ange.200503247" @default.
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