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• W2119338710 endingPage "5317" @default.
• W2119338710 startingPage "5314" @default.
• W2119338710 abstract "The addition of an N-heterocyclic carbene to the carbonyl group of an α,β,γ,δ-unsaturated enol ester affords a hemiacetal azolium intermediate that enables a cascade olefin isomerization/Diels–Alder reaction, for which mechanistic studies implicate Lewis base catalysis. Preliminary studies into the utility of the products have been undertaken with reductive and oxidative cleavage, giving materials for potential use in complex-target synthesis." @default.
• W2119338710 created "2016-06-24" @default.
• W2119338710 creator A5000734125 @default.
• W2119338710 creator A5008812521 @default.
• W2119338710 date "2014-04-06" @default.
• W2119338710 modified "2023-10-02" @default.
• W2119338710 title "Cascade Olefin Isomerization/Intramolecular Diels-Alder Reaction Catalyzed by N-Heterocyclic Carbenes" @default.
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• W2119338710 doi "https://doi.org/10.1002/anie.201402067" @default.
• W2119338710 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24706584" @default.
• W2119338710 hasPublicationYear "2014" @default.
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