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• W2119348510 abstract "Abstract The unprecedented use of a soluble organoindium species, indium(III) hexamethyldisilazide [In(III)(hmds) 3 ], for catalytic carboncarbon bond formations between ketones and boronates, is reported. Various functionalized tertiary homoallyl alcohols were generated easily in high yields. Remarkably, free hydroxy and primary amine functionalities proved to be tolerated. A rate acceleration and markedly improved diastereoselectivities were observed in the presence of methanol. Based on preliminary NMR experiments and the α‐selectivity with an α‐substituted boronate, we assume the in situ generation of reactive allylindium(III) species through catalytic boron‐to‐indium transmetalation." @default.
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• W2119348510 date "2010-06-01" @default.
• W2119348510 modified "2023-10-18" @default.
• W2119348510 title "Catalytic Use of a Soluble Organoindium(III) Species for Allylation and Crotylation of Ketones with Boronates" @default.
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• W2119348510 doi "https://doi.org/10.1002/adsc.201000097" @default.
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