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• W2119542770 startingPage "9466" @default.
• W2119542770 abstract "The independent molecule and ion temperature dependence of the rate coefficient for the H(3)O(+) and (C(2)H(2))(2) reaction producing C(2)H(5)O(+) are determined using a coaxial molecular beam radio frequency ring electrode ion trap (CoMB-RET). The H(3)O(+) temperature is varied from 25 to 170 K, while the equilibrated C(2)H(2)/(C(2)H(2))(2) beam temperatures sampled are 160, 180, 200, and 220 K. The rate coefficient of the H(3)O(+) + (C(2)H(2))(2) reaction is determined to be 4.0 × 10(-10) × (T(react)/300)(-2.5) in the reaction temperature range of T(react) = 114-187 K. The H(3)O(+) and C(2)H(2) radiative association reaction is found to have a rate coefficient below 1 × 10(-13) cm(3)·s(-1) at 187 K. This result is consistent with Herbst's experimental determination." @default.
• W2119542770 created "2016-06-24" @default.
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• W2119542770 date "2012-09-18" @default.
• W2119542770 modified "2023-10-18" @default.
• W2119542770 title "Variable Temperature Rate Studies for the Reaction H3O+ + (C2H2)2 Measured with a Coaxial Molecular Beam Radio Frequency Ring Electrode Ion Trap" @default.
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• W2119542770 doi "https://doi.org/10.1021/jp305936f" @default.
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