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- W2119593204 abstract "The causes of inaccuracy in the values of the successive formation constants for 1:2 metal:ligand complex systems for which K 1 ≤ K 2 are discussed. The experimental error in the [Formula: see text] pL data has been shown to become increasingly important as K 1 /K 2 decreases. It has been concluded that the successive constants cannot be determined if K 1 /K 2 < 10 −2.4 . Their product, K 1 K 2 , can, however, be determined. It is also shown that the value of K 2 cannot be determined for the iron complexes with bipyridyl and 1,10-phenanthroline." @default.
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- W2119593204 date "1972-03-01" @default.
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- W2119593204 title "Anomalous Ratios of Formation Constants: Possible Invalidity in the Successive Constants" @default.
- W2119593204 doi "https://doi.org/10.1139/v72-100" @default.
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