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- W2119759646 abstract "In this paper, we synthesized a novel nucleoside analog by coupling thymine with dimethyl dicarboxylate biphenyl (DDB). The structure of the target compound was determined using 1 H nuclear magnetic resonance (NMR) and electrospray ionization tandem mass spectrometry (ESI-MS/MS). The fragmentation pathways were studied in detail through ESI-MS/MS. By comparing with unsubstituted nucleosides, such as AZT, MCI, d4T and DDI, it was found that the nucleoside analog coupled with DDB would not yield the daughter ions corresponding to the fragments of the nucleoside base and arabinofuranose analogs, but would lose a neutral molecule HF and DDB easily. However, the unsubstituted nucleosides could lightly yield the fragment ions of the nucleoside base and sugar ring. Hence, electrospray ionization mass spectrometry combined with tandem mass spectrometry provides a convenient method to recognize the substituted and unsubstituted nucleosides." @default.
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- W2119759646 date "2004-10-01" @default.
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- W2119759646 title "Characterization of Novel Nucleoside Analogs by Electrospray Ionization Mass Spectra" @default.
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- W2119759646 doi "https://doi.org/10.1255/ejms.678" @default.
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