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- W2119762020 abstract "The oxidation of benzyl alcohol and methoxy-, chloro-, and nitro- substituted benzyl alcohols by permanganate has been studied in aqueous and acetic acid medium in presence of perchloric acid. The reaction is first-order in [MnO4−] and [XC6H4CH2OH], but the order is complex with respect to [H+]. Different thermodynamic parameters have been evaluated. The reaction occurs through the protonation of alcohol in a fast preequilibrium followed by a slow rate-determining oxidation step. A two-electron transfer oxidation step has been suggested for benzyl alcohol and chloro- and nitro- substituted alcohols, while the oxidation of methoxy compounds involves a one-electron transfer via a free-radical mechanism. © 1995 John Wiley & Sons, Inc." @default.
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- W2119762020 date "1995-04-01" @default.
- W2119762020 modified "2023-10-18" @default.
- W2119762020 title "Evidence of protonation during the oxidation of some aryl alcohols by permanganate in perchloric acid medium and mechanism of the oxidation processes" @default.
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- W2119762020 doi "https://doi.org/10.1002/kin.550270409" @default.
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