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- W2119809610 abstract "Abstract 12CaO·7Al 2 O 3 (C12A7, mayenite), which has a nanoscale porous structure that can accommodate extraframework species such as hydride (H − ), oxide (O 2− ), hydroxide (OH − ) ions, and electrons, has been doped with H − ions to investigate its effects as dominant extraframework species. Chemical doping with CaH 2 enables the concentration of H − ions to reach almost the theoretical maximum. The concentration of H − ions is characterized by optical absorption intensity ascribed to photoionization of H − ions, and 1 H magic angle spinning nuclear magnetic resonance (MAS-NMR) spectroscopy. Persistent electron generation, which is accompanied by the formation of an F + absorption band and electrical conductivity, by irradiation with ultraviolet light at room temperature increases as the H − ion doping increases until it reaches half the theoretical maximum and then decreases as the H − ion concentration increases further. This dependence indicates that both H − and O 2− ions are necessary for the generation of persistent electrons." @default.
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- W2119809610 date "2011-06-01" @default.
- W2119809610 modified "2023-09-26" @default.
- W2119809610 title "Heavy doping of H− ion in 12CaO·7Al2O3" @default.
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- W2119809610 doi "https://doi.org/10.1016/j.jssc.2011.04.008" @default.
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